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Resonance-stabilized partial proton transfer in hydrogen bonds of incommensurate Phenazine–chloranilic acid

Authors:

Noohinejad, Leila; Mondal, Swastik; Sk Imran, Ali; Dey, Somnath; van Smaalen, Sander; Schonleber, Andreas

Journal:

Acta Crystallographica, Section B 71 228-234 (2015)

DOI:

https://doi.org/10.1107/S2052520615004084

B-IncStrDB ID: 10522E4Avuq Entry date: 2015-04-02 Last revision: 2021-12-12

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Chemical data

Formula moiety: C12 H8 N2, C6 H2 Cl2 O4 [ Help ]

Structural Formula Sum: C18 H10 Cl2 N2 O4 [ Help ]

Formula weight: 389.2 Da [ Help ]

Crystallographic data and experimental details

Crystal system: monoclinic [ Help ]

Superspace group name: P21(1/2β1/2)0 [ Help ]

Symmetry operations of the superspace group: [ Help ]

Operation code Operation in algebraic form
1 x1,x2,x3,x4
2 -x1,x2+1/2,-x3,-x1-x3+x4

a: 12.3720(2) Å [ Help ]

b: 3.7649(5) Å [ Help ]

c: 16.831(2) Å [ Help ]

α: 90 ° [ Help ]

β: 107.789(7) ° [ Help ]

γ: 90 ° [ Help ]

Volume: 746.52(14) Å3 [ Help ]

Modulation dimension: 1 [ Help ]

Measured independent wave vectors: [ Help ]

Wave vector id q_x q_y q_z
1 0.500000 0.513900 0.500000

Z: 2 [ Help ]

Cell measurement temperature: 139 K [ Help ]

μ: 0.243 mm-1 [ Help ]

Absorption correction type: empirical [ Help ]

Absorption correction remarks: SADABS;Sheldrick,2008 [ Help ]

Minimum transmission factor: 0.7769 [ Help ]

Maximum transmission factor: 0.9910 [ Help ]

Refinement details

Total nb. of reflections: 15433 [ Help ]

Nb. of observed reflections: 8092 [ Help ]

Intense reflections threshold: I>3σ(I) [ Help ]

Refinement based on: F [ Help ]

R(obs): 0.0449 [ Help ]

wR(obs): 0.0677 [ Help ]

R(all): 0.0720 [ Help ]

wR(all): 0.0713 [ Help ]

S(all): 2.08 [ Help ]

S(obs): 2.78 [ Help ]

Nb. of reflections: 15433 [ Help ]

Nb. of parameters: 719 [ Help ]

Weighting scheme: sigma [ Help ]

Weighting scheme remarks: w=1/(σ2(F)+0.0001F2) [ Help ]

Refinement of hydrogen atoms: mixed [ Help ]

Δ/σ(max): 0.0006 [ Help ]

Δ/σ(mean): 0.0001 [ Help ]

Δρ(max): 0.17 e_Å-3 [ Help ]

Δρ(min): -0.02 e_Å-3 [ Help ]

Extinction method: none [ Help ]

Absolute structure remarks: 6649 of Friedel pairs used in the refinement [ Help ]

Flack parameter: 0.5 [ Help ]

Structural Information

Average Structure: [ Help ]

Atom site label Atom symbol x y z ADP type Uiso/equiv Symmetry multiplicity Occupancy Coords from (d)iffraction or (c)alculated Coords restraints or constraints Disordered cluster Disordered group
Cl2 Cl 0.39426(2) 0.759355 0.425664(9) Uani 0.01637(8) 2 1 d ? ? ?
Cl1 Cl 0.10334(2) 1.36699(6) 0.076472(9) Uani 0.01630(8) 2 1 d ? ? ?
O1 O 0.01710(6) 1.0198(3) 0.20084(4) Uani 0.0187(2) 2 1 d ? ? ?
O2 O 0.47869(6) 1.1115(3) 0.30175(3) Uani 0.0182(2) 2 1 d ? ? ?
O3 O 0.14288(6) 0.7382(3) 0.34754(4) Uani 0.0199(2) 2 1 d ? ? ?
O4 O 0.35598(6) 1.3761(3) 0.15557(3) Uani 0.0189(2) 2 1 d ? ? ?
N1 N 0.85572(7) 0.6962(3) 0.24458(4) Uani 0.0134(2) 2 1 d ? ? ?
N2 N 0.64611(7) 0.4400(3) 0.25095(4) Uani 0.0135(2) 2 1 d ? ? ?
C1 C 0.30168(9) 1.2333(3) 0.19627(4) Uani 0.0138(3) 2 1 d ? ? ?
C2 C 0.18097(9) 1.2022(3) 0.17186(4) Uani 0.0135(3) 2 1 d ? ? ?
C3 C 0.12546(9) 1.0428(3) 0.22157(4) Uani 0.0140(3) 2 1 d ? ? ?
C4 C 0.19362(9) 0.8866(3) 0.30527(4) Uani 0.0135(3) 2 1 d ? ? ?
C5 C 0.31591(8) 0.9219(3) 0.33025(4) Uani 0.0125(3) 2 1 d ? ? ?
C6 C 0.36782(8) 1.0814(3) 0.27986(4) Uani 0.0124(3) 2 1 d ? ? ?
C7 C 0.81178(9) 0.5094(3) 0.10230(4) Uani 0.0152(3) 2 1 d ? ? ?
C8 C 0.73694(9) 0.3530(3) 0.03492(4) Uani 0.0167(3) 2 1 d ? ? ?
C9 C 0.63221(9) 0.2204(3) 0.03867(4) Uani 0.0162(3) 2 1 d ? ? ?
C10 C 0.60119(9) 0.2457(3) 0.10984(4) Uani 0.0154(3) 2 1 d ? ? ?
C11 C 0.67723(9) 0.4113(3) 0.18154(4) Uani 0.0136(3) 2 1 d ? ? ?
C12 C 0.78295(8) 0.5441(3) 0.17721(4) Uani 0.0123(3) 2 1 d ? ? ?
C13 C 0.69135(9) 0.6285(3) 0.39302(4) Uani 0.0155(3) 2 1 d ? ? ?
C14 C 0.76521(9) 0.7854(3) 0.46057(4) Uani 0.0172(3) 2 1 d ? ? ?
C15 C 0.87021(9) 0.9210(3) 0.45697(5) Uani 0.0162(3) 2 1 d ? ? ?
C16 C 0.90122(9) 0.8951(3) 0.38591(5) Uani 0.0145(3) 2 1 d ? ? ?
C17 C 0.82595(9) 0.7284(3) 0.31464(4) Uani 0.0129(3) 2 1 d ? ? ?
C18 C 0.71946(9) 0.5983(3) 0.31757(4) Uani 0.0132(3) 2 1 d ? ? ?
H7 H 0.883405 0.595476 0.099163 Uiso 0.0183 2 1 d ? ? ?
H8 H 0.755844 0.332715 -0.016126 Uiso 0.0201 2 1 d ? ? ?
H9 H 0.581407 0.109597 -0.009819 Uiso 0.0194 2 1 d ? ? ?
H10 H 0.529556 0.153698 0.111502 Uiso 0.0185 2 1 d ? ? ?
H13 H 0.620244 0.538221 0.396235 Uiso 0.0186 2 1 d ? ? ?
H14 H 0.745931 0.804454 0.511489 Uiso 0.0207 2 1 d ? ? ?
H15 H 0.920655 1.033441 0.505363 Uiso 0.0194 2 1 d ? ? ?
H16 H 0.972721 0.988108 0.384193 Uiso 0.0174 2 1 d ? ? ?
H1o1 H -0.0461(11) 0.765(4) 0.2321(8) Uiso 0.0281 2 1 d ? ? ?
H1o2 H 0.5251(11) 1.158(4) 0.2704(8) Uiso 0.0273 2 1 d ? ? ?

ADP components: [ Help ]

Atom site label Atom site symbol U11 U22 U33 U12 U13 U23
Cl2 Cl 0.01737(18) 0.01914(12) 0.01152(7) -0.00017(11) 0.00280(9) 0.00293(6)
Cl1 Cl 0.01772(18) 0.01883(12) 0.01129(7) 0.00005(11) 0.00285(9) 0.00285(6)
O1 O 0.0117(4) 0.0259(4) 0.0183(2) -0.0023(4) 0.0042(3) 0.0039(3)
O2 O 0.0132(4) 0.0252(4) 0.0169(2) -0.0030(4) 0.0056(3) 0.0055(3)
O3 O 0.0167(4) 0.0272(4) 0.0177(2) -0.0030(5) 0.0081(3) 0.0054(3)
O4 O 0.0160(4) 0.0254(4) 0.0165(2) -0.0021(5) 0.0067(3) 0.0054(3)
N1 N 0.0132(5) 0.0140(3) 0.0123(2) 0.0001(4) 0.0029(3) 0.0007(2)
N2 N 0.0133(5) 0.0142(3) 0.0127(2) -0.0009(4) 0.0037(3) 0.0005(2)
C1 C 0.0165(6) 0.0137(4) 0.0114(2) -0.0004(5) 0.0044(3) 0.0002(3)
C2 C 0.0144(6) 0.0152(4) 0.0107(2) -0.0016(4) 0.0035(3) 0.0005(2)
C3 C 0.0145(6) 0.0152(4) 0.0122(2) -0.0001(5) 0.0039(3) 0.0000(3)
C4 C 0.0143(6) 0.0150(4) 0.0120(2) -0.0011(5) 0.0050(3) -0.0004(3)
C5 C 0.0125(6) 0.0137(4) 0.0110(2) -0.0009(4) 0.0029(3) 0.0007(2)
C6 C 0.0110(6) 0.0137(4) 0.0118(2) -0.0009(4) 0.0028(3) 0.0002(2)
C7 C 0.0159(6) 0.0159(4) 0.0142(3) -0.0004(5) 0.0051(3) -0.0009(3)
C8 C 0.0187(6) 0.0179(4) 0.0139(2) 0.0045(5) 0.0055(3) 0.0000(3)
C9 C 0.0166(6) 0.0165(4) 0.0138(3) 0.0015(5) 0.0022(3) -0.0020(3)
C10 C 0.0148(6) 0.0164(4) 0.0137(2) -0.0047(5) 0.0023(3) -0.0020(3)
C11 C 0.0161(6) 0.0119(4) 0.0118(2) 0.0000(4) 0.0028(3) 0.0008(2)
C12 C 0.0112(5) 0.0127(4) 0.0130(2) 0.0023(4) 0.0038(3) 0.0018(2)
C13 C 0.0159(6) 0.0180(4) 0.0135(2) 0.0018(5) 0.0060(3) 0.0012(3)
C14 C 0.0200(6) 0.0177(4) 0.0143(3) 0.0006(5) 0.0057(3) -0.0027(3)
C15 C 0.0160(6) 0.0168(4) 0.0143(3) 0.0002(5) 0.0024(3) -0.0028(3)
C16 C 0.0126(6) 0.0144(4) 0.0144(2) 0.0010(5) 0.0009(3) -0.0006(3)
C17 C 0.0144(6) 0.0124(4) 0.0124(2) 0.0018(4) 0.0050(3) 0.0009(2)
C18 C 0.0151(6) 0.0117(4) 0.0117(2) -0.0009(4) 0.0023(3) 0.0007(2)

Fourier Wave Vectors (explicit: q_x,q_y,q_z or coefficients: q_1,q_2,...): [ Help ]

Wave vector code q_1
1 1

Definition of the displacive (translational) Fourier series: [ Help ]

Modulation code Atom site label Displacement axis Wave vector code
Cl2x1 Cl2 x 1
Cl2y1 Cl2 y 1
Cl2z1 Cl2 z 1
Cl1x1 Cl1 x 1
Cl1y1 Cl1 y 1
Cl1z1 Cl1 z 1
O1x1 O1 x 1
O1y1 O1 y 1
O1z1 O1 z 1
O2x1 O2 x 1
O2y1 O2 y 1
O2z1 O2 z 1
O3x1 O3 x 1
O3y1 O3 y 1
O3z1 O3 z 1
O4x1 O4 x 1
O4y1 O4 y 1
O4z1 O4 z 1
N1x1 N1 x 1
N1y1 N1 y 1
N1z1 N1 z 1
N2x1 N2 x 1
N2y1 N2 y 1
N2z1 N2 z 1
C1x1 C1 x 1
C1y1 C1 y 1
C1z1 C1 z 1
C2x1 C2 x 1
C2y1 C2 y 1
C2z1 C2 z 1
C3x1 C3 x 1
C3y1 C3 y 1
C3z1 C3 z 1
C4x1 C4 x 1
C4y1 C4 y 1
C4z1 C4 z 1
C5x1 C5 x 1
C5y1 C5 y 1
C5z1 C5 z 1
C6x1 C6 x 1
C6y1 C6 y 1
C6z1 C6 z 1
C7x1 C7 x 1
C7y1 C7 y 1
C7z1 C7 z 1
C8x1 C8 x 1
C8y1 C8 y 1
C8z1 C8 z 1
C9x1 C9 x 1
C9y1 C9 y 1
C9z1 C9 z 1
C10x1 C10 x 1
C10y1 C10 y 1
C10z1 C10 z 1
C11x1 C11 x 1
C11y1 C11 y 1
C11z1 C11 z 1
C12x1 C12 x 1
C12y1 C12 y 1
C12z1 C12 z 1
C13x1 C13 x 1
C13y1 C13 y 1
C13z1 C13 z 1
C14x1 C14 x 1
C14y1 C14 y 1
C14z1 C14 z 1
C15x1 C15 x 1
C15y1 C15 y 1
C15z1 C15 z 1
C16x1 C16 x 1
C16y1 C16 y 1
C16z1 C16 z 1
C17x1 C17 x 1
C17y1 C17 y 1
C17z1 C17 z 1
C18x1 C18 x 1
C18y1 C18 y 1
C18z1 C18 z 1
H7x1 H7 x 1
H7y1 H7 y 1
H7z1 H7 z 1
H8x1 H8 x 1
H8y1 H8 y 1
H8z1 H8 z 1
H9x1 H9 x 1
H9y1 H9 y 1
H9z1 H9 z 1
H10x1 H10 x 1
H10y1 H10 y 1
H10z1 H10 z 1
H13x1 H13 x 1
H13y1 H13 y 1
H13z1 H13 z 1
H14x1 H14 x 1
H14y1 H14 y 1
H14z1 H14 z 1
H15x1 H15 x 1
H15y1 H15 y 1
H15z1 H15 z 1
H16x1 H16 x 1
H16y1 H16 y 1
H16z1 H16 z 1
H1o1x1 H1o1 x 1
H1o1y1 H1o1 y 1
H1o1z1 H1o1 z 1
H1o2x1 H1o2 x 1
H1o2y1 H1o2 y 1
H1o2z1 H1o2 z 1

Displacive (translational) Fourier coefficients: [ Help ]

Modulation code Cosine coefficient Sine coefficient
Cl2x1 -0.00015(3) 0.00022(3)
Cl2y1 -0.00287(8) 0
Cl2z1 0.00033(2) 0.00038(2)
Cl1x1 -0.00159(7) -0.00190(6)
Cl1y1 -0.00006(8) -0.00111(8)
Cl1z1 0.00060(2) 0.00026(3)
O1x1 -0.00071(9) 0.00026(9)
O1y1 -0.0085(3) 0.0012(3)
O1z1 0.00182(6) -0.00019(8)
O2x1 0.00109(13) -0.00286(9)
O2y1 -0.0034(3) 0.0042(3)
O2z1 0.00043(6) -0.00040(6)
O3x1 -0.00003(8) 0.00034(8)
O3y1 -0.0106(3) 0.0033(4)
O3z1 0.00115(6) -0.00015(7)
O4x1 0.00056(10) -0.00141(8)
O4y1 -0.0030(2) 0.0023(3)
O4z1 -0.00027(7) 0.00101(6)
N1x1 0.00024(10) 0.00090(10)
N1y1 0.0008(3) 0.0009(3)
N1z1 -0.00031(9) 0.00174(7)
N2x1 -0.00173(9) -0.00022(11)
N2y1 0.0000(3) 0.0004(3)
N2z1 0.00115(7) 0.00055(8)
C1x1 -0.00029(17) -0.00353(12)
C1y1 -0.0009(3) 0.0011(3)
C1z1 0.00009(9) 0.00025(8)
C2x1 -0.00077(13) -0.00154(12)
C2y1 -0.0005(3) 0.0003(3)
C2z1 0.00059(8) 0.00019(8)
C3x1 -0.00335(13) -0.00084(16)
C3y1 -0.0035(3) -0.0005(3)
C3z1 0.00072(8) 0.00024(9)
C4x1 -0.00102(14) 0.00018(12)
C4y1 -0.0046(3) -0.0008(4)
C4z1 0.00105(9) 0.00047(9)
C5x1 -0.00138(12) -0.00113(13)
C5y1 -0.0026(3) -0.0010(3)
C5z1 0.00054(8) 0.00054(8)
C6x1 -0.00044(15) -0.00270(12)
C6y1 -0.0014(3) 0.0011(3)
C6z1 0.00019(8) 0.00016(8)
C7x1 -0.00057(12) 0.00026(12)
C7y1 0.0007(3) -0.0039(3)
C7z1 0.00187(10) 0.00150(10)
C8x1 0.00023(12) 0.00068(12)
C8y1 -0.0016(3) -0.0044(3)
C8z1 0.00156(8) -0.00023(10)
C9x1 0.00056(12) 0.00064(12)
C9y1 -0.0020(3) -0.0015(3)
C9z1 0.00083(9) -0.00110(9)
C10x1 -0.00124(12) -0.00007(12)
C10y1 -0.0002(3) -0.0012(3)
C10z1 0.00052(9) -0.00111(8)
C11x1 -0.00115(12) -0.00050(14)
C11y1 0.0004(3) -0.0007(3)
C11z1 0.00137(8) 0.00021(10)
C12x1 -0.00037(12) -0.00073(12)
C12y1 0.0010(3) -0.0003(3)
C12z1 0.00166(10) 0.00160(10)
C13x1 0.00011(12) -0.00118(12)
C13y1 0.0003(3) 0.0010(3)
C13z1 -0.00015(9) 0.00127(8)
C14x1 0.00120(12) -0.00117(12)
C14y1 0.0015(3) -0.0019(3)
C14z1 -0.00129(9) 0.00080(9)
C15x1 0.00073(13) 0.00000(12)
C15y1 0.0035(3) -0.0010(3)
C15z1 -0.00157(9) 0.00005(10)
C16x1 0.00190(14) -0.00008(13)
C16y1 0.0040(3) -0.0013(3)
C16z1 -0.00135(9) 0.00033(9)
C17x1 0.00098(12) -0.00106(13)
C17y1 0.0009(3) -0.0008(3)
C17z1 -0.00021(9) 0.00074(9)
C18x1 -0.00038(13) -0.00169(12)
C18y1 0.0005(3) 0.0008(3)
C18z1 0.00019(9) 0.00092(8)
H7x1 -0.0006 0.0005
H7y1 0.0026 -0.0056
H7z1 0.001 0.0028
H8x1 0.0008 0.0007
H8y1 -0.0021 -0.0066
H8z1 0.0017 -0.0004
H9x1 0.0013 -0.0001
H9y1 -0.0036 0.0003
H9z1 -0.0001 -0.0013
H10x1 -0.0017 0.0006
H10y1 0.0017 -0.0008
H10z1 -0.0006 -0.001
H13x1 -0.0006 -0.0012
H13y1 0.0014 0.0014
H13z1 0.0003 0.0011
H14x1 0.0014 -0.0013
H14y1 0.0024 -0.0019
H14z1 -0.0014 0.0004
H15x1 0.0002 0.0001
H15y1 0.0052 0.0019
H15z1 -0.0014 -0.0008
H16x1 0.0015 0.0009
H16y1 0.005 0.0011
H16z1 -0.0015 -0.0003
H1o1x1 -0.0064(12) 0.0151(12)
H1o1y1 -0.003(4) 0.014(3)
H1o1z1 0.0020(8) 0.0010(9)
H1o2x1 0.0000(12) -0.0006(12)
H1o2y1 -0.003(3) 0.004(3)
H1o2z1 -0.0017(9) -0.0006(9)

Definition of the ADP Fourier series: [ Help ]

Modulation code Atom site label Tensor element Wave vector code
Cl2U111 Cl2 U11 1
Cl2U221 Cl2 U22 1
Cl2U331 Cl2 U33 1
Cl2U121 Cl2 U12 1
Cl2U131 Cl2 U13 1
Cl2U231 Cl2 U23 1
Cl1U111 Cl1 U11 1
Cl1U221 Cl1 U22 1
Cl1U331 Cl1 U33 1
Cl1U121 Cl1 U12 1
Cl1U131 Cl1 U13 1
Cl1U231 Cl1 U23 1
O1U111 O1 U11 1
O1U221 O1 U22 1
O1U331 O1 U33 1
O1U121 O1 U12 1
O1U131 O1 U13 1
O1U231 O1 U23 1
O2U111 O2 U11 1
O2U221 O2 U22 1
O2U331 O2 U33 1
O2U121 O2 U12 1
O2U131 O2 U13 1
O2U231 O2 U23 1
O3U111 O3 U11 1
O3U221 O3 U22 1
O3U331 O3 U33 1
O3U121 O3 U12 1
O3U131 O3 U13 1
O3U231 O3 U23 1
O4U111 O4 U11 1
O4U221 O4 U22 1
O4U331 O4 U33 1
O4U121 O4 U12 1
O4U131 O4 U13 1
O4U231 O4 U23 1
N1U111 N1 U11 1
N1U221 N1 U22 1
N1U331 N1 U33 1
N1U121 N1 U12 1
N1U131 N1 U13 1
N1U231 N1 U23 1
N2U111 N2 U11 1
N2U221 N2 U22 1
N2U331 N2 U33 1
N2U121 N2 U12 1
N2U131 N2 U13 1
N2U231 N2 U23 1
C1U111 C1 U11 1
C1U221 C1 U22 1
C1U331 C1 U33 1
C1U121 C1 U12 1
C1U131 C1 U13 1
C1U231 C1 U23 1
C2U111 C2 U11 1
C2U221 C2 U22 1
C2U331 C2 U33 1
C2U121 C2 U12 1
C2U131 C2 U13 1
C2U231 C2 U23 1
C3U111 C3 U11 1
C3U221 C3 U22 1
C3U331 C3 U33 1
C3U121 C3 U12 1
C3U131 C3 U13 1
C3U231 C3 U23 1
C4U111 C4 U11 1
C4U221 C4 U22 1
C4U331 C4 U33 1
C4U121 C4 U12 1
C4U131 C4 U13 1
C4U231 C4 U23 1
C5U111 C5 U11 1
C5U221 C5 U22 1
C5U331 C5 U33 1
C5U121 C5 U12 1
C5U131 C5 U13 1
C5U231 C5 U23 1
C6U111 C6 U11 1
C6U221 C6 U22 1
C6U331 C6 U33 1
C6U121 C6 U12 1
C6U131 C6 U13 1
C6U231 C6 U23 1
C7U111 C7 U11 1
C7U221 C7 U22 1
C7U331 C7 U33 1
C7U121 C7 U12 1
C7U131 C7 U13 1
C7U231 C7 U23 1
C8U111 C8 U11 1
C8U221 C8 U22 1
C8U331 C8 U33 1
C8U121 C8 U12 1
C8U131 C8 U13 1
C8U231 C8 U23 1
C9U111 C9 U11 1
C9U221 C9 U22 1
C9U331 C9 U33 1
C9U121 C9 U12 1
C9U131 C9 U13 1
C9U231 C9 U23 1
C10U111 C10 U11 1
C10U221 C10 U22 1
C10U331 C10 U33 1
C10U121 C10 U12 1
C10U131 C10 U13 1
C10U231 C10 U23 1
C11U111 C11 U11 1
C11U221 C11 U22 1
C11U331 C11 U33 1
C11U121 C11 U12 1
C11U131 C11 U13 1
C11U231 C11 U23 1
C12U111 C12 U11 1
C12U221 C12 U22 1
C12U331 C12 U33 1
C12U121 C12 U12 1
C12U131 C12 U13 1
C12U231 C12 U23 1
C13U111 C13 U11 1
C13U221 C13 U22 1
C13U331 C13 U33 1
C13U121 C13 U12 1
C13U131 C13 U13 1
C13U231 C13 U23 1
C14U111 C14 U11 1
C14U221 C14 U22 1
C14U331 C14 U33 1
C14U121 C14 U12 1
C14U131 C14 U13 1
C14U231 C14 U23 1
C15U111 C15 U11 1
C15U221 C15 U22 1
C15U331 C15 U33 1
C15U121 C15 U12 1
C15U131 C15 U13 1
C15U231 C15 U23 1
C16U111 C16 U11 1
C16U221 C16 U22 1
C16U331 C16 U33 1
C16U121 C16 U12 1
C16U131 C16 U13 1
C16U231 C16 U23 1
C17U111 C17 U11 1
C17U221 C17 U22 1
C17U331 C17 U33 1
C17U121 C17 U12 1
C17U131 C17 U13 1
C17U231 C17 U23 1
C18U111 C18 U11 1
C18U221 C18 U22 1
C18U331 C18 U33 1
C18U121 C18 U12 1
C18U131 C18 U13 1
C18U231 C18 U23 1

ADP Fourier coefficients: [ Help ]

Modulation code Cosine coefficient Sine coefficient
Cl2U111 0.0021(2) 0.0032(2)
Cl2U221 -0.00196(17) -0.00022(16)
Cl2U331 -0.00069(18) 0.00007(18)
Cl2U121 0.00006(14) 0.00000(15)
Cl2U131 -0.00065(16) 0.00024(17)
Cl2U231 0.00021(11) 0.00049(11)
Cl1U111 -0.0007(2) 0.0017(2)
Cl1U221 -0.00023(16) -0.00089(15)
Cl1U331 -0.00047(18) -0.00044(17)
Cl1U121 -0.00050(17) -0.00150(17)
Cl1U131 -0.00097(17) -0.00058(16)
Cl1U231 0.00067(11) 0.00029(12)
O1U111 0.0037(7) 0.0026(7)
O1U221 -0.0035(6) 0.0004(5)
O1U331 0.0001(6) -0.0007(6)
O1U121 -0.0010(4) 0.0002(4)
O1U131 0.0010(5) 0.0012(5)
O1U231 0.0020(4) 0.0001(4)
O2U111 0.0009(7) 0.0001(7)
O2U221 -0.0024(5) 0.0037(5)
O2U331 -0.0004(6) 0.0002(6)
O2U121 0.0002(4) -0.0028(5)
O2U131 -0.0002(5) -0.0007(5)
O2U231 0.0008(4) -0.0008(4)
O3U111 0.0055(7) -0.0025(7)
O3U221 -0.0061(6) 0.0019(6)
O3U331 -0.0011(6) 0.0002(6)
O3U121 0.0007(5) 0.0008(4)
O3U131 0.0001(5) 0.0008(5)
O3U231 0.0029(4) 0.0003(4)
O4U111 0.0013(7) 0.0002(7)
O4U221 -0.0011(6) 0.0019(5)
O4U331 -0.0002(6) -0.0009(6)
O4U121 0.0012(4) -0.0007(5)
O4U131 0.0018(5) 0.0003(5)
O4U231 -0.0007(4) 0.0012(4)
N1U111 -0.0024(8) -0.0004(8)
N1U221 0.0013(5) 0.0000(5)
N1U331 -0.0001(6) -0.0016(6)
N1U121 -0.0012(5) -0.0002(5)
N1U131 -0.0016(6) -0.0029(6)
N1U231 -0.0014(4) 0.0022(4)
N2U111 -0.0007(7) 0.0020(8)
N2U221 0.0005(5) -0.0005(5)
N2U331 -0.0001(6) 0.0005(6)
N2U121 -0.0015(5) -0.0003(5)
N2U131 -0.0019(5) 0.0002(6)
N2U231 0.0016(4) 0.0005(4)
C1U111 -0.0030(10) 0.0107(10)
C1U221 -0.0001(6) 0.0011(6)
C1U331 0.0004(7) -0.0032(7)
C1U121 0.0006(6) -0.0030(6)
C1U131 -0.0010(7) -0.0016(7)
C1U231 -0.0003(4) 0.0006(4)
C2U111 -0.0025(9) -0.0024(10)
C2U221 -0.0001(6) 0.0019(6)
C2U331 -0.0004(7) -0.0020(7)
C2U121 0.0004(6) -0.0020(6)
C2U131 -0.0013(7) -0.0024(7)
C2U231 0.0009(4) -0.0002(4)
C3U111 0.0026(10) 0.0014(10)
C3U221 -0.0031(6) 0.0000(6)
C3U331 -0.0002(7) -0.0009(8)
C3U121 -0.0029(6) -0.0020(6)
C3U131 0.0004(7) -0.0001(7)
C3U231 0.0010(4) 0.0005(5)
C4U111 0.0042(10) 0.0006(9)
C4U221 -0.0029(7) 0.0001(6)
C4U331 -0.0015(8) 0.0012(7)
C4U121 -0.0015(6) 0.0022(6)
C4U131 -0.0016(7) 0.0020(7)
C4U231 0.0003(4) -0.0003(5)
C5U111 -0.0004(9) -0.0053(9)
C5U221 -0.0005(6) -0.0006(6)
C5U331 -0.0015(7) 0.0021(7)
C5U121 -0.0010(6) 0.0016(6)
C5U131 -0.0005(6) 0.0004(7)
C5U231 -0.0003(4) 0.0030(4)
C6U111 0.0059(10) 0.0030(9)
C6U221 -0.0002(6) 0.0002(6)
C6U331 -0.0011(7) 0.0003(7)
C6U121 0.0007(5) -0.0023(6)
C6U131 -0.0005(7) -0.0003(7)
C6U231 0.0008(4) 0.0008(4)
C7U111 0.0021(9) 0.0032(10)
C7U221 -0.0011(6) -0.0017(6)
C7U331 0.0007(7) -0.0005(7)
C7U121 0.0016(6) 0.0001(6)
C7U131 -0.0005(7) -0.0012(7)
C7U231 0.0020(5) 0.0022(5)
C8U111 0.0002(10) 0.0037(11)
C8U221 -0.0024(6) -0.0040(7)
C8U331 0.0020(7) 0.0009(8)
C8U121 -0.0012(6) -0.0013(6)
C8U131 0.0009(7) 0.0009(7)
C8U231 0.0030(5) -0.0001(5)
C9U111 0.0142(10) 0.0048(10)
C9U221 -0.0009(6) 0.0002(6)
C9U331 -0.0038(8) -0.0014(8)
C9U121 0.0013(6) -0.0003(6)
C9U131 0.0024(7) 0.0009(7)
C9U231 0.0006(5) -0.0007(5)
C10U111 -0.0011(10) -0.0042(9)
C10U221 0.0003(6) 0.0009(6)
C10U331 -0.0004(8) -0.0004(7)
C10U121 0.0012(6) -0.0022(6)
C10U131 -0.0034(7) -0.0014(7)
C10U231 0.0024(5) -0.0020(5)
C11U111 -0.0014(9) 0.0037(11)
C11U221 0.0000(6) -0.0007(6)
C11U331 -0.0008(7) 0.0003(8)
C11U121 -0.0008(6) -0.0011(5)
C11U131 0.0000(6) -0.0007(7)
C11U231 0.0021(4) -0.0005(4)
C12U111 0.0015(9) 0.0023(9)
C12U221 0.0004(6) -0.0002(6)
C12U331 0.0007(7) -0.0006(7)
C12U121 -0.0022(5) -0.0002(5)
C12U131 -0.0005(7) 0.0001(6)
C12U231 0.0014(4) 0.0018(4)
C13U111 -0.0003(9) 0.0045(10)
C13U221 0.0007(7) 0.0005(6)
C13U331 0.0000(7) -0.0020(7)
C13U121 -0.0013(6) 0.0004(6)
C13U131 -0.0003(7) -0.0011(7)
C13U231 0.0002(5) 0.0016(5)
C14U111 -0.0012(10) -0.0021(10)
C14U221 -0.0008(6) -0.0015(7)
C14U331 0.0024(8) -0.0002(8)
C14U121 -0.0023(6) -0.0022(6)
C14U131 0.0019(7) -0.0019(7)
C14U231 -0.0014(5) 0.0012(5)
C15U111 0.0044(11) -0.0004(9)
C15U221 0.0025(6) 0.0002(6)
C15U331 -0.0004(8) -0.0020(7)
C15U121 0.0021(6) 0.0017(6)
C15U131 0.0010(7) -0.0018(7)
C15U231 -0.0010(5) -0.0007(5)
C16U111 -0.0013(11) 0.0023(8)
C16U221 0.0014(6) -0.0013(6)
C16U331 0.0017(8) 0.0000(7)
C16U121 0.0011(5) -0.0005(6)
C16U131 0.0009(7) -0.0007(6)
C16U231 -0.0012(4) 0.0001(5)
C17U111 -0.0060(9) 0.0049(9)
C17U221 0.0003(6) -0.0011(6)
C17U331 0.0011(7) -0.0005(7)
C17U121 0.0032(5) -0.0002(6)
C17U131 -0.0014(7) 0.0007(7)
C17U231 0.0001(4) 0.0012(4)
C18U111 -0.0001(9) 0.0015(9)
C18U221 0.0010(6) -0.0001(6)
C18U331 -0.0009(7) -0.0012(7)
C18U121 -0.0012(6) -0.0013(5)
C18U131 0.0000(6) -0.0005(7)
C18U231 0.0005(4) 0.0021(4)