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#\#CIF_1.0 ################################################################################ # # # This CIF is a part of the B-IncStrDB # # (Bilbao Incommensurate Structures Database) # # http://www.cryst.ehu.eus/bincstrdb/ # # # # Please note that the structure of the CIF file may differ from the one # # deposited, as it may have been modified to comply with the standard. The # # file has been validated against official dictionaries as well as local # # dictionaries including non-standard data names used by SHELXL (Sheldrick, # # G. M. (2008). Acta Cryst. A 64, 112-122) and JANA (Petricek, V., Dusek, M. # # and Palatinus, L. (2014), Z. Kristallogr. 229, 345-352). # # # # For comments and/or criticisms, please e-mail to administrador-bcs@ehu.es # # # ################################################################################ #======================================================================= data_global #======================================================================= _audit_creation_method 'Jana2006 Version : 15/03/2013' # 2. SUBMISSION DETAILS _publ_contact_author_name 'Hadermann, Joke' _publ_contact_author_address ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium ; _publ_contact_author_email 'j.hadermann@ua.ac.be' _publ_contact_author_fax '+32-32653257' _publ_contact_author_phone '+32-32653245' #======================================================================= # 2. TITLE AND AUTHOR LIST _journal_name_full 'Chemistry of Materials' _journal_year 2013 _journal_volume 25 _journal_page_first 4387 _journal_page_last 4395 _journal_paper_doi https://dx.doi.org/10.1021/cm402729r _publ_section_title ;Incommensurate Modulation and Luminescence in the CaGd~2(1-x)~Eu~2x~(MoO~4~)~4(1-y)~(WO~4~)~4y~ (0≤x≤1, 0≤y≤1) Red Phosphors ; loop_ _publ_author_name _publ_author_address 'Morozov, Vladimir A.' ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium Chemistry Department Moscow State University 119991 Moscow Russia ; 'Bertha, Anne' ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium ; 'Meert, Katrien W.' ;Lumilab Department of Solid State Sciences Ghent University B-9000 Ghent Belgium Center for Nano- and Biophotonics (NB-Photonics) Ghent University B-9000 Ghent Belgium ; 'Van Rompaey, Senne' ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium ; 'Batuk, Dmitry' ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium ; 'Martinez, Gerardo T.' ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium ; 'Van Aert, Sandra' ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium ; 'Smet, Philippe F.' ;Lumilab Department of Solid State Sciences Ghent University B-9000 Ghent Belgium Center for Nano- and Biophotonics (NB-Photonics) Ghent University B-9000 Ghent Belgium ; 'Raskina, Maria V.' ;Chemistry Department Moscow State University 119991 Moscow Russia ; 'Poelman, Dirk' ;Lumilab Department of Solid State Sciences Ghent University B-9000 Ghent Belgium Center for Nano- and Biophotonics (NB-Photonics) Ghent University B-9000 Ghent Belgium ; 'Abakumov, Artem M.' ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium ; 'Hadermann, Joke' ;EMAT University of Antwerp Groenenborgerlaan 171 Antwerp B-2020 Belgium ; #======================================================================= _publ_section_references ;Petricek, V., Dusek, M. & Palatinus L. (2006). Jana2006. Structure Determination Software Programs. Institute of Physics, Praha, Czech Republic. Palatinus L. & Chapuis G. (2007). J. Appl. Cryst. 40, 786-790. ; #======================================================================= data_I #======================================================================= # 5. CHEMICAL DATA _chemical_name_common Ca0.25Eu0.5WO4 _chemical_formula_moiety "(Ca2+)0.25,(Eu3+)0.5,(MoO4 2-)" _chemical_formula_structural Ca0.25Eu0.5WO4 _chemical_formula_analytical Ca0.25Eu0.5WO4 _chemical_formula_iupac Ca0.25Eu0.5WO4 _chemical_formula_sum 'Ca0.25 Eu0.5 O4 W1' _chemical_formula_weight 333.8 #======================================================================= # 6. CRYSTAL DATA _space_group_crystal_system monoclinic _space_group_ssg_name 'I2/b(\a\b0)00' loop_ _space_group_symop_ssg_id _space_group_symop_ssg_operation_algebraic 1 x1,x2,x3,x4 2 -x1,-x2+1/2,x3,-x4 3 -x1,-x2,-x3,-x4 4 x1,x2+1/2,-x3,x4 5 x1+1/2,x2+1/2,x3+1/2,x4 6 -x1+1/2,-x2,x3+1/2,-x4 7 -x1+1/2,-x2+1/2,-x3+1/2,-x4 8 x1+1/2,x2,-x3+1/2,x4 _cell_length_a 5.2365(2) _cell_length_b 5.2629(2) _cell_length_c 11.4547(4) _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 91.152(2) _cell_volume 315.62(2) _cell_modulation_dimension 1 loop_ _cell_wave_vector_seq_id _cell_wave_vector_x _cell_wave_vector_y _cell_wave_vector_z 1 0.561516 -1.229056 0.000000 _cell_formula_units_Z 4 _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _cell_measurement_temperature 293 _exptl_crystal_type_of_structure mod _exptl_crystal_density_diffrn 7.0235 _exptl_crystal_density_meas ? _exptl_crystal_density_method ? _exptl_crystal_F_000 570 _exptl_absorpt_coefficient_mu 0 _exptl_crystal_description ? _exptl_crystal_size_max ? _exptl_crystal_size_mid ? _exptl_crystal_size_min ? _exptl_crystal_size_rad ? _exptl_crystal_colour ? _exptl_absorpt_correction_type ? _exptl_absorpt_process_details ? _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? #======================================================================= # 7. EXPERIMENTAL DATA _exptl_special_details ? _diffrn_ambient_temperature 293 _diffrn_source_power ? _diffrn_source_voltage 200 _diffrn_source_current ? _diffrn_radiation_type 'electron' _diffrn_source 'Philips CM20' _diffrn_radiation_wavelength 0.025 _diffrn_radiation_monochromator ? _diffrn_measurement_device 'Philips CM20' _diffrn_measurement_device_type 'Transmission electron microscope' _diffrn_detector ? _diffrn_detector_area_resol_mean ? _diffrn_measurement_method ? _diffrn_measurement_specimen_support ? _diffrn_reflns_number 457 _diffrn_reflns_theta_min 0.13 _diffrn_reflns_theta_max 1.48 _diffrn_reflns_theta_full 0.4 _diffrn_measured_fraction_theta_max 0.05 _diffrn_measured_fraction_theta_full 0.27 _diffrn_reflns_av_R_equivalents ? _diffrn_reflns_av_unetI/netI 0.0056 _diffrn_reflns_limit_h_min -9 _diffrn_reflns_limit_h_max 8 _diffrn_reflns_limit_k_min -9 _diffrn_reflns_limit_k_max 10 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_limit_index_m_1_min -1 _diffrn_reflns_limit_index_m_1_max 1 _diffrn_reflns_reduction_process ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_radiation_probe electron #======================================================================= # 8. REFINEMENT DATA _reflns_number_total 457 _reflns_number_gt 457 _reflns_threshold_expression 'I>0\s(I)' _refine_ls_structure_factor_coef F _refine_ls_R_factor_gt 0.1791 _refine_ls_wR_factor_gt 0.2597 _refine_ls_R_factor_all 0.1791 _refine_ls_wR_factor_ref 0.2597 _refine_ls_goodness_of_fit_ref 21.97 _refine_ls_goodness_of_fit_gt 21.97 _refine_ls_restrained_S_gt ? _refine_ls_restrained_S_all ? _refine_ls_number_reflns 457 _refine_ls_number_parameters 8 _refine_ls_number_restraints 2 _refine_ls_number_constraints 2 _refine_ls_weighting_scheme sigma _refine_ls_weighting_details 'w=1/(\s^2^(F)+0.0001F^2^)' _refine_ls_hydrogen_treatment ? _refine_ls_shift/su_max 0.0090 _refine_ls_shift/su_mean 0.0030 _refine_diff_density_max ? _refine_diff_density_min ? _refine_ls_extinction_method 'none' _refine_ls_extinction_coef ? _refine_ls_abs_structure_details ? _refine_ls_abs_structure_Flack ? _refine_ls_abs_structure_Rogers ? _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution ? _computing_structure_refinement ? _computing_molecular_graphics ? _computing_publication_material ? #======================================================================= # 9. ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS loop_ _atom_type_symbol Ca Eu W O loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_adp_type _atom_site_U_iso_or_equiv _atom_site_site_symmetry_multiplicity _atom_site_occupancy _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_disorder_assembly _atom_site_disorder_group Ca1 Ca 0.5 0.25 0.8681(17) Uiso 0 8 0.0625 d . . . Ca2 Ca 0.5 0.25 0.8681(17) Uiso 0 8 0.0625 d . . . Eu Eu 0.5 0.25 0.8681(17) Uiso 0 4 0.5 d . . . W W 0.5 0.25 0.3798(10) Uiso 0 4 1 d . . . O1 O 0.363(3) 0.028(3) 0.284(2) Uiso 0 8 1 d . . . O2 O 0.272(3) 0.365(4) 0.473(2) Uiso 0 8 1 d . . . loop_ _atom_site_occ_special_func_atom_site_label _atom_site_occ_special_func_crenel_c _atom_site_occ_special_func_crenel_w Ca1 0.6875 0.125 Ca2 0.3125 0.125 Eu 0 0.5 #======================================================================= # 10. MOLECULAR GEOMETRY loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_ssg_symmetry_1 _geom_bond_site_ssg_symmetry_2 _geom_bond_distance_av _geom_bond_distance_min _geom_bond_distance_max _geom_bond_publ_flag Ca1 O1 . 5_5555 2.56(2) 2.56(2) 2.56(2) ? Ca1 O1 . 6_5555 2.56(2) 2.56(2) 2.56(2) ? Ca1 O1 . 3_6565 2.39(3) 2.39(3) 2.39(3) ? Ca1 O1 . 4_5565 2.39(3) 2.39(3) 2.39(3) ? Ca1 O2 . 5_5455 2.78(2) 2.78(2) 2.78(2) ? Ca1 O2 . 6_5655 2.78(2) 2.78(2) 2.78(2) ? Ca1 O2 . 7_5565 2.38(3) 2.38(3) 2.38(3) ? Ca1 O2 . 8_5565 2.38(3) 2.38(3) 2.38(3) ? Ca2 O1 . 5_5555 2.56(2) 2.56(2) 2.56(2) ? Ca2 O1 . 6_5555 2.56(2) 2.56(2) 2.56(2) ? Ca2 O1 . 3_6565 2.39(3) 2.39(3) 2.39(3) ? Ca2 O1 . 4_5565 2.39(3) 2.39(3) 2.39(3) ? Ca2 O2 . 5_5455 2.78(2) 2.78(2) 2.78(2) ? Ca2 O2 . 6_5655 2.78(2) 2.78(2) 2.78(2) ? Ca2 O2 . 7_5565 2.38(3) 2.38(3) 2.38(3) ? Ca2 O2 . 8_5565 2.38(3) 2.38(3) 2.38(3) ? Eu O1 . 5_5555 2.56(2) 2.56(2) 2.56(2) ? Eu O1 . 6_5555 2.56(2) 2.56(2) 2.56(2) ? Eu O1 . 3_6565 2.39(3) 2.39(3) 2.39(3) ? Eu O1 . 4_5565 2.39(3) 2.39(3) 2.39(3) ? Eu O2 . 5_5455 2.78(2) 2.78(2) 2.78(2) ? Eu O2 . 6_5655 2.78(2) 2.78(2) 2.78(2) ? Eu O2 . 7_5565 2.38(3) 2.38(3) 2.38(3) ? Eu O2 . 8_5565 2.38(3) 2.38(3) 2.38(3) ? W O1 . . 1.75(2) 1.75(2) 1.75(2) ? W O1 . 2_6555 1.75(2) 1.75(2) 1.75(2) ? W O1 . 7_5555 2.93(2) 2.93(2) 2.93(2) ? W O1 . 8_5555 2.93(2) 2.93(2) 2.93(2) ? W O2 . . 1.72(2) 1.72(2) 1.72(2) ? W O2 . 2_6555 1.72(2) 1.72(2) 1.72(2) ? W O2 . 3_6665 2.87(2) 2.87(2) 2.87(2) ? W O2 . 4_5465 2.87(2) 2.87(2) 2.87(2) ? #======================================================================= # 11. STRUCTURE-FACTOR LIST loop_ _refln_index_h _refln_index_k _refln_index_l _refln_index_m_1 _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_include_status 4 4 8 0 214.72 120.26 4.64 o 3 4 7 0 2.57 84.16 3.71 o 4 3 7 0 92.34 118.03 2.78 o 5 2 7 0 1.68 33.87 1.86 o 1 5 6 0 383.45 260.55 5.38 o 2 4 6 0 2.95 47.42 1.86 o 3 3 6 0 328.67 154.40 2.88 o 0 5 5 0 4.50 49.83 2.69 o 1 4 5 0 2.92 29.14 1.48 o 2 3 5 0 29.38 69.59 1.86 o 3 2 5 0 60.75 221.86 3.06 o 4 1 5 0 0.05 43.80 1.76 o -2 6 4 0 144.24 96.04 3.90 o -1 5 4 0 6.00 265.47 3.71 o 0 4 4 0 635.40 564.82 4.73 o 1 3 4 0 3.39 55.58 1.58 o 2 2 4 0 884.36 407.72 3.62 o 3 1 4 0 0.07 38.14 1.58 o 4 0 4 0 546.30 642.29 5.01 o -3 6 3 0 33.25 39.16 2.13 o -2 5 3 0 22.29 42.22 1.76 o -1 4 3 0 19.96 111.07 2.23 o 0 3 3 0 68.00 52.43 1.48 o 1 2 3 0 114.84 93.44 1.67 o 2 1 3 0 205.15 253.13 2.51 o 3 0 3 0 1.81 60.13 1.58 o 4 -1 3 0 127.39 259.35 3.25 o -3 5 2 0 290.56 326.25 4.27 o -2 4 2 0 84.15 64.67 1.95 o -1 3 2 0 611.25 571.50 4.08 o 0 2 2 0 123.78 169.06 1.86 o 1 1 2 0 2599.66 1297.21 4.36 o 2 0 2 0 74.68 166.28 1.86 o 3 -1 2 0 1067.01 772.48 4.83 o -5 6 1 0 12.51 36.10 3.06 o -4 5 1 0 2.88 18.74 2.04 o -3 4 1 0 43.77 41.01 1.76 o -2 3 1 0 1.23 28.02 1.76 o -1 2 1 0 19.38 134.55 1.76 o 0 1 1 0 111.31 251.00 1.58 o 1 0 1 0 183.10 253.78 1.58 o 2 -1 1 0 186.88 321.43 2.60 o 3 -2 1 0 193.61 201.82 2.69 o 4 -3 1 0 52.41 159.13 2.78 o -4 4 0 0 162.76 89.17 3.71 o -2 2 0 0 1283.49 1254.25 5.66 o 2 -2 0 0 1283.49 1254.25 5.66 o -5 4 -1 0 0.21 53.82 3.15 o -4 3 -1 0 52.41 159.13 2.78 o -3 2 -1 0 193.61 201.82 2.69 o -2 1 -1 0 186.88 321.43 2.60 o -1 0 -1 0 183.10 253.78 1.58 o 0 -1 -1 0 111.31 251.00 1.58 o 1 -2 -1 0 19.38 134.55 1.76 o 3 -4 -1 0 43.77 41.01 1.76 o -5 3 -2 0 324.02 454.12 6.96 o -4 2 -2 0 0.44 23.38 2.04 o -3 1 -2 0 1067.01 772.48 4.83 o -2 0 -2 0 74.68 166.28 1.86 o -1 -1 -2 0 2599.66 1297.21 4.36 o 0 -2 -2 0 123.78 169.06 1.86 o 1 -3 -2 0 611.25 571.50 4.08 o 2 -4 -2 0 84.15 64.67 1.95 o 3 -5 -2 0 290.56 326.25 4.27 o -5 2 -3 0 21.58 72.84 3.34 o -4 1 -3 0 127.39 259.35 3.25 o -3 0 -3 0 1.81 60.13 1.58 o -2 -1 -3 0 205.15 253.13 2.51 o -1 -2 -3 0 114.84 93.44 1.67 o 0 -3 -3 0 68.00 52.43 1.48 o 1 -4 -3 0 19.96 111.07 2.23 o 2 -5 -3 0 22.29 42.22 1.76 o 3 -6 -3 0 33.25 39.16 2.13 o -6 2 -4 0 412.58 133.80 4.36 o -5 1 -4 0 12.52 128.51 3.80 o -4 0 -4 0 546.30 642.29 5.01 o -3 -1 -4 0 0.07 38.14 1.58 o -2 -2 -4 0 884.36 407.72 3.62 o -1 -3 -4 0 3.39 55.58 1.58 o 0 -4 -4 0 635.40 564.82 4.73 o 1 -5 -4 0 6.00 265.47 3.71 o -6 1 -5 0 27.82 124.15 4.08 o -4 -1 -5 0 0.05 43.80 1.76 o -3 -2 -5 0 60.75 221.86 3.06 o -2 -3 -5 0 29.38 69.59 1.86 o -1 -4 -5 0 2.92 29.14 1.48 o -5 -1 -6 0 104.33 173.80 4.64 o -3 -3 -6 0 328.67 154.40 2.88 o -2 -4 -6 0 2.95 47.42 1.86 o -6 -1 -7 0 32.17 51.13 3.15 o -5 -2 -7 0 1.68 33.87 1.86 o -4 -3 -7 0 92.34 118.03 2.78 o -6 -2 -8 0 192.71 134.64 4.73 o -7 -2 -9 0 6.86 53.91 3.80 o -8 2 0 -1 4.99 28.45 0.98 o -8 4 0 0 153.37 110.89 1.08 o -8 0 0 -1 5.34 23.27 1.10 o -8 2 0 0 194.85 167.71 1.20 o -8 0 0 0 282.60 152.84 1.78 o -6 6 0 0 156.91 164.86 1.70 o -6 4 0 0 366.21 173.44 1.19 o -6 0 0 -1 7.96 28.79 0.67 o -6 2 0 0 111.05 281.36 1.36 o -6 0 0 0 266.73 275.36 1.33 o -6 -4 0 -1 7.03 37.55 1.28 o -6 -2 0 0 347.71 332.24 1.48 o -6 0 0 1 10.79 21.42 0.94 o -6 -4 0 0 258.55 252.88 1.46 o -6 -6 0 0 164.88 159.71 1.84 o -4 4 0 -1 7.58 28.08 0.71 o -4 6 0 0 156.49 261.23 2.00 o -4 2 0 -1 11.05 44.73 0.61 o -4 4 0 0 162.76 241.75 1.27 o -4 6 0 1 10.11 28.92 0.64 o -4 0 0 -1 14.90 46.16 0.65 o -4 2 0 0 1051.64 523.90 1.52 o -4 4 0 1 17.08 44.62 0.56 o -4 0 0 0 636.73 572.76 1.51 o -4 -4 0 -1 11.61 36.02 0.71 o -4 -2 0 0 731.08 661.37 1.70 o -4 -4 0 0 93.29 273.60 1.34 o -4 -6 0 0 294.68 228.39 1.31 o -4 -4 0 1 8.76 36.01 0.67 o -4 -8 0 0 184.29 178.98 1.27 o -4 -6 0 1 5.89 23.75 0.66 o -2 8 0 0 63.76 211.49 1.83 o -2 6 0 0 521.44 326.81 2.01 o -2 8 0 1 7.56 28.18 1.20 o -2 2 0 -1 19.39 53.02 0.89 o -2 4 0 0 598.56 749.44 2.53 o -2 6 0 1 13.63 29.42 0.92 o -2 0 0 -1 35.76 62.86 0.51 o -2 2 0 0 1283.49 1290.70 2.68 o -2 4 0 1 31.05 46.25 0.80 o -2 -2 0 -1 38.34 38.06 0.52 o -2 0 0 0 1042.15 1087.22 1.48 o -2 2 0 1 77.09 63.41 0.37 o -2 -4 0 -1 21.89 115.07 0.79 o -2 -2 0 0 1156.29 1340.01 1.93 o -2 0 0 1 62.07 38.66 0.37 o -2 -4 0 0 1071.05 630.02 1.65 o -2 -6 0 0 193.86 371.60 1.51 o -2 -4 0 1 11.42 23.86 0.61 o -2 -8 0 0 162.59 182.27 1.26 o 0 8 0 0 264.81 157.38 1.67 o 0 4 0 -1 12.26 17.69 0.78 o 0 6 0 0 187.52 271.94 1.30 o 0 2 0 -1 28.53 22.81 0.60 o 0 4 0 0 606.65 704.32 1.65 o 0 0 0 -1 97.91 93.40 0.55 o 0 2 0 0 1305.31 1280.17 2.28 o 0 4 0 1 35.60 45.21 0.53 o 0 -2 0 -1 139.91 91.14 0.34 o 0 2 0 1 139.91 91.14 0.34 o 0 -4 0 -1 35.60 45.21 0.53 o 0 -4 0 0 606.65 704.32 1.65 o 0 -6 0 0 187.52 271.94 1.30 o 2 8 0 0 162.59 182.27 1.26 o 2 4 0 -1 11.42 23.86 0.61 o 2 6 0 0 193.86 371.60 1.51 o 2 8 0 1 6.89 21.26 1.06 o 2 2 0 -1 24.67 37.92 0.79 o 2 4 0 0 1071.05 630.02 1.65 o 2 6 0 1 11.37 40.97 1.12 o 2 0 0 -1 62.07 38.66 0.37 o 2 2 0 0 1156.29 1340.01 1.93 o 2 4 0 1 21.89 115.07 0.79 o 2 -2 0 -1 77.09 63.41 0.37 o 2 0 0 0 1042.15 1087.22 1.48 o 2 2 0 1 38.34 38.06 0.52 o 2 0 0 1 35.76 62.86 0.51 o 4 10 0 0 138.19 67.05 1.37 o 4 6 0 -1 5.89 23.75 0.66 o 4 8 0 0 184.29 178.98 1.27 o 4 4 0 -1 8.76 36.01 0.67 o 4 6 0 0 294.68 228.39 1.31 o 4 4 0 0 93.29 273.60 1.34 o 4 2 0 0 731.08 661.37 1.70 o 4 4 0 1 11.61 36.02 0.71 o 4 -2 0 -1 25.13 21.97 0.73 o 4 0 0 0 636.73 572.76 1.51 o 4 -4 0 -1 17.08 44.62 0.56 o 4 -2 0 0 1051.64 523.90 1.52 o 4 0 0 1 14.90 46.16 0.65 o 4 -6 0 -1 10.11 28.92 0.64 o 4 -4 0 0 162.76 241.75 1.27 o 4 -2 0 1 11.05 44.73 0.61 o 4 -4 0 1 7.58 28.08 0.71 o 6 4 0 0 258.55 252.88 1.46 o 6 2 0 0 347.71 332.24 1.48 o 6 0 0 0 266.73 275.36 1.33 o 6 -2 0 0 111.05 281.36 1.36 o 6 0 0 1 7.96 28.79 0.67 o 6 -6 0 -1 7.06 13.58 0.87 o 6 -4 0 0 366.21 173.44 1.19 o 6 -2 0 1 6.90 22.40 1.06 o 8 -2 0 0 194.85 167.71 1.20 o 8 -4 0 0 153.37 110.89 1.08 o 4 4 16 0 210.29 63.67 2.40 o 6 2 16 0 77.11 67.96 1.75 o 0 6 12 0 103.48 66.89 2.90 o 2 4 12 0 260.06 261.49 2.31 o 4 2 12 0 237.52 279.46 2.45 o 6 0 12 0 144.60 91.23 1.95 o -2 6 8 0 186.39 254.92 2.40 o -1 5 8 0 8.59 24.84 1.21 o 0 4 8 0 279.24 277.79 2.34 o 2 2 8 0 508.06 532.55 2.62 o 3 1 8 0 2.90 53.52 1.24 o 4 0 8 0 385.71 351.25 2.43 o -4 6 4 0 234.93 290.77 2.45 o -2 4 4 0 438.41 446.29 2.51 o 0 2 4 0 1663.33 1085.94 2.85 o 1 1 4 0 111.56 275.17 1.38 o 2 0 4 0 1928.65 1395.57 3.19 o 4 -2 4 0 261.73 445.86 2.51 o -4 4 0 0 162.76 230.56 2.34 o -2 2 0 0 1283.49 973.96 2.76 o 2 -2 0 0 1283.49 973.96 2.76 o 4 -4 0 0 162.76 230.56 2.34 o -6 4 -4 0 111.33 314.26 3.69 o -4 2 -4 0 261.73 445.86 2.51 o -2 0 -4 0 1928.65 1395.57 3.19 o -1 -1 -4 0 111.56 275.17 1.38 o 0 -2 -4 0 1663.33 1085.94 2.85 o 2 -4 -4 0 438.41 446.29 2.51 o 4 -6 -4 0 234.93 290.77 2.45 o -6 2 -8 0 173.08 398.52 4.00 o -4 0 -8 0 385.71 351.25 2.43 o -3 -1 -8 0 2.90 53.52 1.24 o -2 -2 -8 0 508.06 532.55 2.62 o -1 -3 -8 0 2.83 65.42 1.92 o 0 -4 -8 0 279.24 277.79 2.34 o 1 -5 -8 0 8.59 24.84 1.21 o 2 -6 -8 0 186.39 254.92 2.40 o -6 0 -12 0 144.60 91.23 1.95 o -4 -2 -12 0 237.52 279.46 2.45 o -2 -4 -12 0 260.06 261.49 2.31 o -6 -2 -16 0 77.11 67.96 1.75 o 1 7 10 0 74.22 100.01 2.31 o -4 8 8 0 134.37 79.11 2.03 o 0 6 8 0 200.79 196.54 2.72 o 4 4 8 0 214.72 187.62 1.91 o -5 7 6 0 67.38 75.19 1.55 o -1 5 6 0 147.22 250.90 1.94 o 3 3 6 0 328.67 369.51 2.19 o 7 1 6 0 215.16 206.49 2.01 o -6 6 4 0 149.41 126.52 1.66 o -2 4 4 0 438.41 740.45 2.84 o 2 2 4 0 884.36 818.38 2.54 o 6 0 4 0 303.83 348.38 2.26 o -7 5 2 0 184.91 141.93 2.95 o -3 3 2 0 685.74 752.33 2.70 o 1 1 2 0 2599.66 2089.97 2.81 o 5 -1 2 0 319.26 535.25 2.51 o -4 2 0 0 1051.64 742.32 2.72 o 4 -2 0 0 1051.64 742.32 2.72 o -5 1 -2 0 319.26 535.25 2.51 o -1 -1 -2 0 2599.66 2089.97 2.81 o 3 -3 -2 0 685.74 752.33 2.70 o -6 0 -4 0 303.83 348.38 2.26 o -2 -2 -4 0 884.36 818.38 2.54 o 2 -4 -4 0 438.41 740.45 2.84 o 6 -6 -4 0 149.41 126.52 1.66 o -7 -1 -6 0 215.16 206.49 2.01 o -3 -3 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1663.33 1335.28 4.71 o 2 2 4 0 884.36 657.94 3.88 o 4 2 4 0 392.32 564.34 4.26 o 6 2 4 0 205.39 323.54 3.94 o -9 1 2 0 183.96 205.07 5.79 o -7 1 2 0 199.15 528.10 6.99 o -5 1 2 0 319.26 575.98 4.32 o -3 1 2 0 1067.01 1187.18 4.90 o -1 1 2 0 2895.24 1299.67 3.62 o 1 1 2 0 2599.66 1766.41 4.26 o 3 1 2 0 652.49 1023.70 4.58 o 5 1 2 0 532.71 706.08 4.77 o -8 0 0 0 282.60 352.79 6.36 o -6 0 0 0 266.73 305.22 3.69 o -4 0 0 0 636.73 661.70 4.13 o -2 0 0 0 1042.15 987.90 3.50 o 2 0 0 0 1042.15 987.90 3.50 o 4 0 0 0 636.73 661.70 4.13 o 6 0 0 0 266.73 305.22 3.69 o -9 -1 -2 0 140.17 186.18 6.23 o -7 -1 -2 0 190.93 371.35 5.98 o -5 -1 -2 0 532.71 706.08 4.77 o -3 -1 -2 0 652.49 1023.70 4.58 o -1 -1 -2 0 2599.66 1766.41 4.26 o 1 -1 -2 0 2895.24 1299.67 3.62 o 3 -1 -2 0 1067.01 1187.18 4.90 o 5 -1 -2 0 319.26 575.98 4.32 o -8 -2 -4 0 257.44 248.06 6.04 o -6 -2 -4 0 205.39 323.54 3.94 o -4 -2 -4 0 392.32 564.34 4.26 o -2 -2 -4 0 884.36 657.94 3.88 o 0 -2 -4 0 1663.33 1335.28 4.71 o 2 -2 -4 0 887.20 521.67 3.37 o 4 -2 -4 0 261.73 617.06 4.39 o 6 -2 -4 0 412.58 317.75 3.82 o -9 -3 -6 0 101.21 86.29 4.13 o -7 -3 -6 0 212.02 235.91 5.47 o -5 -3 -6 0 299.93 403.27 4.32 o -3 -3 -6 0 328.67 364.36 3.75 o -1 -3 -6 0 328.97 616.67 4.13 o 1 -3 -6 0 1270.89 754.98 4.45 o 3 -3 -6 0 272.95 348.84 3.56 o 5 -3 -6 0 247.83 350.56 3.82 o -6 -4 -8 0 170.56 170.48 3.82 o -4 -4 -8 0 214.72 240.11 3.75 o -2 -4 -8 0 319.93 331.04 3.75 o 0 -4 -8 0 279.24 429.98 4.01 o 2 -4 -8 0 344.87 431.25 4.01 o 4 -4 -8 0 223.25 222.62 3.50 o -3 -5 -10 0 160.54 174.93 3.50 o -1 -5 -10 0 155.08 214.86 3.56 o 1 -5 -10 0 352.85 267.07 3.75 o 3 -5 -10 0 142.58 186.18 3.24 o 5 -5 -10 0 84.71 131.05 3.18 o 4 4 8 0 214.72 176.75 2.10 o 7 1 10 0 101.71 141.13 1.99 o 0 6 4 0 362.61 369.56 2.54 o 3 3 6 0 328.67 332.92 2.33 o 6 0 8 0 181.19 314.23 2.52 o -4 8 0 0 195.54 163.25 2.02 o -1 5 2 0 518.10 644.19 2.94 o 2 2 4 0 884.36 730.81 2.62 o 5 -1 6 0 472.95 711.99 3.25 o -5 7 -2 0 199.92 163.33 2.99 o -2 4 0 0 598.56 738.62 2.91 o 1 1 2 0 2599.66 1549.00 2.57 o 4 -2 4 0 261.73 654.47 2.86 o -6 6 -4 0 149.41 189.14 3.09 o -3 3 -2 0 685.74 742.45 2.88 o 3 -3 2 0 685.74 742.45 2.88 o -4 2 -4 0 261.73 654.47 2.86 o -1 -1 -2 0 2599.66 1549.00 2.57 o 2 -4 0 0 598.56 738.62 2.91 o -5 1 -6 0 472.95 711.99 3.25 o -2 -2 -4 0 884.36 730.81 2.62 o 1 -5 -2 0 518.10 644.19 2.94 o 4 -8 0 0 195.54 163.25 2.02 o -6 0 -8 0 181.19 314.23 2.52 o -3 -3 -6 0 328.67 332.92 2.33 o 0 -6 -4 0 362.61 369.56 2.54 o 3 -9 -2 0 118.08 93.56 2.70 o -7 -1 -10 0 101.71 141.13 1.99 o -4 -4 -8 0 214.72 176.75 2.10 o -1 -7 -6 0 277.92 123.99 2.54 o -8 -2 -12 0 62.34 88.69 2.78 o -3 9 2 0 118.08 85.93 2.22 o 0 8 0 0 264.81 121.09 2.47 o -3 7 2 0 177.48 169.50 1.83 o -6 6 4 0 149.41 130.77 1.94 o 3 7 -2 0 236.62 235.35 3.08 o 0 6 0 0 187.52 252.83 2.04 o -3 5 2 0 290.56 282.49 2.11 o -6 4 4 0 111.33 504.34 3.01 o 6 6 -4 0 149.45 138.39 2.68 o 3 5 -2 0 281.38 395.71 2.42 o 0 4 0 0 606.65 717.58 2.68 o -3 3 2 0 685.74 726.68 2.80 o -6 2 4 0 412.58 273.11 2.32 o 6 4 -4 0 143.23 257.77 2.19 o 3 3 -2 0 626.21 608.92 2.57 o 0 2 0 0 1305.31 926.80 2.14 o -3 1 2 0 1067.01 1099.20 2.98 o -6 0 4 0 303.83 328.22 2.34 o 6 2 -4 0 205.39 193.45 1.91 o 3 1 -2 0 652.49 786.72 2.55 o -3 -1 2 0 652.49 786.72 2.55 o -6 -2 4 0 205.39 193.45 1.91 o 6 0 -4 0 303.83 328.22 2.34 o 3 -1 -2 0 1067.01 1099.20 2.98 o 0 -2 0 0 1305.31 926.80 2.14 o -3 -3 2 0 626.21 608.92 2.57 o -6 -4 4 0 143.23 257.77 2.19 o 6 -2 -4 0 412.58 273.11 2.32 o 3 -3 -2 0 685.74 726.68 2.80 o 0 -4 0 0 606.65 717.58 2.68 o -3 -5 2 0 281.38 395.71 2.42 o 6 -4 -4 0 111.33 504.34 3.01 o 3 -5 -2 0 290.56 282.49 2.11 o 0 -6 0 0 187.52 252.83 2.04 o 6 -6 -4 0 149.41 130.77 1.94 o 3 -7 -2 0 177.48 169.50 1.83 o 6 -8 -4 0 108.65 61.37 2.68 o 0 8 4 0 109.54 495.50 4.48 o -3 7 2 0 177.48 251.55 1.40 o -6 6 0 0 156.91 56.91 1.28 o 2 6 4 0 310.91 244.18 1.36 o -1 5 2 0 518.10 663.21 1.85 o 7 5 6 0 56.69 80.84 1.27 o -4 4 0 0 162.76 170.48 1.09 o 0 4 2 0 116.52 142.85 0.87 o 4 4 4 0 524.95 380.80 1.55 o -7 3 -2 0 199.52 198.23 2.85 o 1 3 2 0 1127.13 1225.93 2.03 o -2 2 0 0 1283.49 1247.97 2.19 o 6 2 4 0 205.39 208.06 1.21 o -5 1 -2 0 319.26 388.30 1.43 o 3 1 2 0 652.49 981.68 1.81 o -8 0 -4 0 104.02 216.92 3.06 o -4 0 -2 0 128.15 160.65 0.88 o 4 0 2 0 128.15 160.65 0.88 o 8 0 4 0 104.02 210.28 2.24 o -7 -1 -4 0 8.59 51.05 1.04 o -3 -1 -2 0 652.49 981.68 1.81 o 5 -1 2 0 319.26 388.30 1.43 o -6 -2 -4 0 205.39 208.06 1.21 o 2 -2 0 0 1283.49 1268.02 3.03 o -5 -3 -4 0 7.21 21.08 0.84 o -1 -3 -2 0 1127.13 1225.93 2.03 o -4 -4 -4 0 524.95 380.80 1.55 o 0 -4 -2 0 116.52 142.85 0.87 o 4 -4 0 0 162.76 170.48 1.09 o -7 -5 -6 0 56.69 80.84 1.27 o 1 -5 -2 0 518.10 663.21 1.85 o -2 -6 -4 0 310.91 244.18 1.36 o 2 -6 -2 0 1.07 9.03 0.76 o 6 -6 0 0 156.91 55.52 0.92 o -1 -7 -4 0 0.76 40.61 1.24 o 3 -7 -2 0 177.48 251.55 1.40 o 5 -9 -2 0 131.04 29.09 1.24 o