#\#CIF_2.0
# Created by the Bilbao Crystallographic Server
# http://www.cryst.ehu.es
# Date: 14/03/2021 

data_5yOhtAoR
_audit_creation_date            2021-03-14
_audit_creation_method          "Bilbao Crystallographic Server"

_citation_journal_abbrev        "Solid State Communications"
_citation_journal_volume        55
_citation_page_first            887
_citation_page_last             890
_citation_article_id            .
_citation_year                  1985
_citation_DOI                   10.1016/0038-1098(85)90200-5

loop_
_citation_author_name
"A. de Kozak"
"M. Samouel"
"M. Leblanc"
"G. Ferey"
"J.Pannetier"

_atomic_positions_source_database_code_ICSD  61798
_atomic_positions_source_other               .

_transition_temperature  19
_experiment_temperature  4.5

loop_
_irrep_id
_irrep_dimension
_irrep_small_dimension
_irrep_direction_type
_irrep_action
_irrep_modes_number
_irrep_presence
mGM1+  1  1  .  primary  6  .

_exptl_crystal_magnetic_properties_details
;
NPD
FM along b
Canted FM
;

_active_magnetic_irreps_details
;
1k magnetic structure
k-maximal magnetic symmetry
1-dim irrep as primary
;

_parent_space_group.name_H-M_alt  'P 2_1/c'
_parent_space_group.IT_number                       14
_parent_space_group.transform_Pp_abc  'a,b,-a+c;0,0,0'

loop_
_parent_propagation_vector.id
_parent_propagation_vector.kxkykz
k1 [0 0 0]

_parent_space_group.child_transform_Pp_abc  'a,b,c;0,0,0'
_space_group_magn.transform_BNS_Pp_abc  'a,b,-a+c;0,0,0'



_space_group_magn.number_BNS  14.75
_space_group_magn.name_BNS  "P 2_1/c"
_cell_length_a             7.32360
_cell_length_b             17.45250
_cell_length_c             5.45860
_cell_angle_alpha          90.00
_cell_angle_beta           91.84
_cell_angle_gamma          90.00

loop_
_space_group_symop_magn_operation.id
_space_group_symop_magn_operation.xyz
1 x,y,z,+1 
2 -x+1/2,y+1/2,-z+1/2,+1 
3 -x,-y,-z,+1 
4 x+1/2,-y+1/2,z+1/2,+1 

loop_
_space_group_symop_magn_centering.id
_space_group_symop_magn_centering.xyz
1 x,y,z,+1 

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Fe1 Fe 0.40920 0.62490 0.23090
Fe2 Fe 0.26980 0.41960 0.26200
Na1 Na 0.30110 0.03770 0.75570
Ba1 Ba 0.06020 0.28560 0.73310
F1 F 0.13830 0.41960 0.95710
F2 F 0.99950 0.92260 0.41640
F3 F 0.28110 0.31110 0.29560
F4 F 0.44230 0.91930 0.04230
F5 F 0.27730 0.16510 0.48810
F6 F 0.20860 0.16480 0.99400
F7 F 0.24010 0.03100 0.24550
F8 F 0.43330 0.29140 0.81350
F9 F 0.40000 0.43170 0.57770

loop_
_atom_site_moment.label
_atom_site_moment.crystalaxis_x
_atom_site_moment.crystalaxis_y
_atom_site_moment.crystalaxis_z
_atom_site_moment.symmform
_atom_site_moment.magnitude
Fe1 2.49(3) 0.02(7) -2.51(3) mx,my,mz 3.60(4)
Fe2 -2.64(3) 0.33(9) 2.36(4) mx,my,mz 3.61(6)

