#\#CIF_2.0
# Created by the Bilbao Crystallographic Server
# http://www.cryst.ehu.es
# Date: 09/09/2018 23:34:49

data_5yOhtAoR
_audit_creation_date            2018-09-09
_audit_creation_method          "Bilbao Crystallographic Server"

_citation_journal_abbrev        "Inorg. Chem."
_citation_journal_volume        56
_citation_page_first            2750
_citation_page_last             2762
_citation_article_id            ?
_citation_year                  2017
_citation_DOI                   10.1021/acs.inorgchem.6b02905

loop_
_citation_author_name
"Xu,D"
"Avdeev, M."
"Battle, P.D."

_atomic_positions_source_database_code_ICSD  .
_atomic_positions_source_other               .

_Neel_temperature  8
_magn_diffrn_temperature  1.6

loop_
_irrep_id
_irrep_dimension
_irrep_small_dimension
_irrep_direction_type
_irrep_action
_irrep_modes_number
_irrep_presence
mGM2+  1  1  .  primary  2  .

_exptl_crystal_magnetic_properties_details
;
NPD
;

_active_magnetic_irreps_details
;
k-maximal magnetic symmetry (6 possible)
1-dim irrep active: one to one relation between irrep and MSG
An oblique spin component on the xy plane is symmetry allowed
;

_parent_space_group.name_H-M  'P  4/n  b  m'
_parent_space_group.IT_number                       125
_parent_space_group.transform_to_standard_Pp_abc  'a,b,c;0,0,0'

loop_
_magnetic_propagation_vector_seq_id
_magnetic_propagation_vector_kxkykz
k1 0,0,0

_magnetic_space_group.transform_from_parent_Pp_abc  'a,b,c;0,0,0'
_magnetic_space_group.transform_to_standard_Pp_abc  'a,b,c;0,0,0'



_space_group.magn_number_BNS  125.367
_space_group.magn_name_BNS  "P  4'/n  b  m'"
_cell_length_a             9.83170
_cell_length_b             9.83170
_cell_length_c             4.90240
_cell_angle_alpha          90.00
_cell_angle_beta           90.00
_cell_angle_gamma          90.00

loop_
_space_group_symop.magn_id
_space_group_symop.magn_operation_xyz
_space_group_symop.magn_operation_mxmymz
1 x,y,z,+1 mx,my,mz
2 x,-y+1/2,-z,+1 mx,-my,-mz
3 -x+1/2,y,-z,+1 -mx,my,-mz
4 -x+1/2,-y+1/2,z,+1 -mx,-my,mz
5 -x,-y,-z,+1 mx,my,mz
6 -x,y+1/2,z,+1 mx,-my,-mz
7 x+1/2,-y,z,+1 -mx,my,-mz
8 x+1/2,y+1/2,-z,+1 -mx,-my,mz
9 -y+1/2,x,z,-1 my,-mx,-mz
10 y,-x+1/2,z,-1 -my,mx,-mz
11 y,x,-z,-1 -my,-mx,mz
12 -y+1/2,-x+1/2,-z,-1 my,mx,mz
13 y+1/2,-x,-z,-1 my,-mx,-mz
14 -y,x+1/2,-z,-1 -my,mx,-mz
15 -y,-x,z,-1 -my,-mx,mz
16 y+1/2,x+1/2,z,-1 my,mx,mz

loop_
_space_group_symop.magn_centering_id
_space_group_symop.magn_centering_xyz
_space_group_symop.magn_centering_mxmymz
1 x,y,z,+1 mx,my,mz


loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_fract_symmform
Ce1 Ce   2 b  0.25000  0.25000  0.50000  1.00000 0,0,0     
Mn1 Mn   4 f  0.00000  0.00000  0.50000  1.00000 0,0,0     
Ge1 Ge   8 k  0.52340  0.25000  0.00000  1.00000 Dx,0,0    
O1  O    8 m  0.63020  0.36980  0.17100  1.00000 Dx,-Dx,Dz 
O2  O   16 n  0.16690  0.06470  0.25500  1.00000 Dx,Dy,Dz  

loop_
_atom_site_moment.label
_atom_site_moment.crystalaxis_x
_atom_site_moment.crystalaxis_y
_atom_site_moment.crystalaxis_z
_atom_site_moment.symmform
Mn1  0.00000  0.00000  4.61000 Mx,-Mx,Mz 

# end of cif
